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One of the properties of gases is that they mix with each other. When they do so, they become a solution—a homogeneous mixture. Some of the properties of gas mixtures are easy to determine if we know the composition of the gases in the mix.
In gas mixtures, each component in the gas phase can be treated separately. Each component of the mixture shares the same temperature and volume. (Remember that gases expand to fill the volume of their container; gases in a mixture continue to do that as well.) However, each gas has its own pressure. The partial pressureThe pressure that an individual gas in a mixture has. of a gas, P_{i}, is the pressure that an individual gas in a mixture has. Partial pressures are expressed in torr, millimeters of mercury, or atmospheres like any other gas pressure; however, we use the term pressure when talking about pure gases and the term partial pressure when we are talking about the individual gas components in a mixture.
Dalton’s law of partial pressuresThe total pressure of a gas mixture, ${P}_{\text{tot}}$, is equal to the sum of the partial pressures of the components, ${P}_{\text{i}}$. states that the total pressure of a gas mixture, P_{tot}, is equal to the sum of the partial pressures of the components, P_{i}:
$${P}_{\text{tot}}={P}_{1}+{P}_{2}+{P}_{3}+\dots ={\displaystyle \sum _{\#\text{ofgases}}{P}_{\text{i}}}$$Although this may seem to be a trivial law, it reinforces the idea that gases behave independently of each other.
A mixture of H_{2} at 2.33 atm and N_{2} at 0.77 atm is in a container. What is the total pressure in the container?
Solution
Dalton’s law of partial pressures states that the total pressure is equal to the sum of the partial pressures. We simply add the two pressures together:
P_{tot} = 2.33 atm + 0.77 atm = 3.10 atmTest Yourself
Air can be thought of as a mixture of N_{2} and O_{2}. In 760 torr of air, the partial pressure of N_{2} is 608 torr. What is the partial pressure of O_{2}?
Answer
152 torr
A 2.00 L container with 2.50 atm of H_{2} is connected to a 5.00 L container with 1.90 atm of O_{2} inside. The containers are opened, and the gases mix. What is the final pressure inside the containers?
Solution
Because gases act independently of each other, we can determine the resulting final pressures using Boyle’s law and then add the two resulting pressures together to get the final pressure. The total final volume is 2.00 L + 5.00 L = 7.00 L. First, we use Boyle’s law to determine the final pressure of H_{2}:
(2.50 atm)(2.00 L) = P_{2}(7.00 L)Solving for P_{2}, we get
P_{2} = 0.714 atm = partial pressure of H_{2}Now we do that same thing for the O_{2}:
(1.90 atm)(5.00 L) = P_{2}(7.00 L) P_{2} = 1.36 atm = partial pressure of O_{2}The total pressure is the sum of the two resulting partial pressures:
P_{tot} = 0.714 atm + 1.36 atm = 2.07 atmTest Yourself
If 0.75 atm of He in a 2.00 L container is connected to a 3.00 L container with 0.35 atm of Ne and the containers are opened, what is the resulting total pressure?
Answer
0.51 atm
One of the reasons we have to deal with Dalton’s law of partial pressures is because gases are frequently collected by bubbling through water. As we will see in Chapter 10 "Solids and Liquids", liquids are constantly evaporating into a vapor until the vapor achieves a partial pressure characteristic of the substance and the temperature. This partial pressure is called a vapor pressureThe partial pressure exerted by evaporation of a liquid.. Table 6.2 "Vapor Pressure of Water versus Temperature" lists the vapor pressures of H_{2}O versus temperature. Note that if a substance is normally a gas under a given set of conditions, the term partial pressure is used; the term vapor pressure is reserved for the partial pressure of a vapor when the liquid is the normal phase under a given set of conditions.
Table 6.2 Vapor Pressure of Water versus Temperature
Temperature (°C) | Vapor Pressure (torr) | Temperature (°C) | Vapor Pressure (torr) | |
---|---|---|---|---|
5 | 6.54 | 30 | 31.84 | |
10 | 9.21 | 35 | 42.20 | |
15 | 12.79 | 40 | 55.36 | |
20 | 17.54 | 50 | 92.59 | |
21 | 18.66 | 60 | 149.5 | |
22 | 19.84 | 70 | 233.8 | |
23 | 21.08 | 80 | 355.3 | |
24 | 22.39 | 90 | 525.9 | |
25 | 23.77 | 100 | 760.0 |
Any time a gas is collected over water, the total pressure is equal to the partial pressure of the gas plus the vapor pressure of water. This means that the amount of gas collected will be less than the total pressure suggests.
Hydrogen gas is generated by the reaction of nitric acid and elemental iron. The gas is collected in an inverted 2.00 L container immersed in a pool of water at 22°C. At the end of the collection, the partial pressure inside the container is 733 torr. How many moles of H_{2} gas were generated?
Solution
We need to take into account that the total pressure includes the vapor pressure of water. According to Table 6.2 "Vapor Pressure of Water versus Temperature", the vapor pressure of water at 22°C is 19.84 torr. According to Dalton’s law of partial pressures, the total pressure equals the sum of the pressures of the individual gases, so
$$\text{733torr}={P}_{{\text{H}}_{2}}+{P}_{{\text{H}}_{\text{2}}\text{O}}={P}_{{\text{H}}_{\text{2}}}+\text{19}.\text{84torr}$$We solve by subtracting:
$${P}_{{\text{H}}_{\text{2}}}=\text{713torr}$$Now we can use the ideal gas law to determine the number of moles (remembering to convert temperature to kelvins, making it 295 K):
$$\text{(713torr)(2}\text{.00L)}=n\left(62.36\text{}\frac{\text{L}\cdot \text{atm}}{\text{mol}\cdot \text{K}}\right)(\text{295K)}$$All the units cancel except for mol, which is what we are looking for. So
n = 0.0775 mol H_{2} collectedTest Yourself
CO_{2}, generated by the decomposition of CaCO_{3}, is collected in a 3.50 L container over water. If the temperature is 50°C and the total pressure inside the container is 833 torr, how many moles of CO_{2} were generated?
Answer
0.129 mol
Finally, we introduce a new unit that can be useful, especially for gases. The mole fractionThe ratio of the number of moles of a component in a mixture divided by the total number of moles in the sample., χ_{i}, is the ratio of the number of moles of component i in a mixture divided by the total number of moles in the sample:
$${\chi}_{\text{i}}=\frac{\text{molesofcomponent}i}{\text{totalnumberofmoles}}$$(χ is the lowercase Greek letter chi.) Note that mole fraction is not a percentage; its values range from 0 to 1. For example, consider the combination of 4.00 g of He and 5.0 g of Ne. Converting both to moles, we get
$$\text{4}\text{.00}\overline{)\text{gHe}}\text{\hspace{0.17em}}\times \text{\hspace{0.17em}}\frac{\text{1molHe}}{4.00\overline{)\text{gHe}}}=1.00\text{molHeand5}\text{.0}\overline{)\text{gNe}}\text{\hspace{0.17em}}\times \text{\hspace{0.17em}}\frac{\text{1molNe}}{20.0\overline{)\text{gNe}}}=0.25\text{molNe}$$The total number of moles is the sum of the two mole amounts:
total moles = 1.00 mol + 0.025 mol = 1.25 molThe mole fractions are simply the ratio of each mole amount and the total number of moles, 1.25 mol:
$$\begin{array}{l}{\chi}_{\text{He}}=\frac{1.00\text{}\overline{)\text{mol}}}{1.25\text{}\overline{)\text{mol}}}=0.800\\ {\chi}_{\text{Ne}}=\frac{0.25\text{}\overline{)\text{mol}}}{1.25\text{}\overline{)\text{mol}}}=0.200\end{array}$$The sum of the mole fractions equals exactly 1.
For gases, there is another way to determine the mole fraction. When gases have the same volume and temperature (as they would in a mixture of gases), the number of moles is proportional to partial pressure, so the mole fractions for a gas mixture can be determined by taking the ratio of partial pressure to total pressure:
$${\chi}_{\text{i}}=\frac{{P}_{\text{i}}}{{P}_{\text{tot}}}$$This expression allows us to determine mole fractions without calculating the moles of each component directly.
A container has a mixture of He at 0.80 atm and Ne at 0.60 atm. What are the mole fractions of each component?
Solution
According to Dalton’s law, the total pressure is the sum of the partial pressures:
P_{tot} = 0.80 atm + 0.60 atm = 1.40 atmThe mole fractions are the ratios of the partial pressure of each component and the total pressure:
$$\begin{array}{l}{\chi}_{\text{He}}=\frac{0.80\text{atm}}{\text{1}\text{.40atm}}=0.57\\ {\chi}_{\text{Ne}}=\frac{0.60\text{atm}}{\text{1}\text{.40atm}}=0.43\end{array}$$Again, the sum of the mole fractions is exactly 1.
Test Yourself
What are the mole fractions when 0.65 atm of O_{2} and 1.30 atm of N_{2} are mixed in a container?
Answer
${\chi}_{{\text{O}}_{\text{2}}}=0.\text{33};\text{}{\chi}_{{\text{N}}_{\text{2}}}=0.\text{67}$
Carbonated beverages—sodas, beer, sparkling wines—have one thing in common: they have CO_{2} gas dissolved in them in such sufficient quantities that it affects the drinking experience. Most people find the drinking experience pleasant—indeed, in the United States alone, over 1.5 × 10^{9} gal of soda are consumed each year, which is almost 50 gal per person! This figure does not include other types of carbonated beverages, so the total consumption is probably significantly higher.
All carbonated beverages are made in one of two ways. First, the flat beverage is subjected to a high pressure of CO_{2} gas, which forces the gas into solution. The carbonated beverage is then packaged in a tightly-sealed package (usually a bottle or a can) and sold. When the container is opened, the CO_{2} pressure is released, resulting in the well-known hiss of an opening container, and CO_{2} bubbles come out of solution. This must be done with care: if the CO_{2} comes out too violently, a mess can occur!
If you are not careful opening a container of a carbonated beverage, you can make a mess as the CO_{2} comes out of solution suddenly.
© Thinkstock
The second way a beverage can become carbonated is by the ingestion of sugar by yeast, which then generates CO_{2} as a digestion product. This process is called fermentation. The overall reaction is
C_{6}H_{12}O_{6}(aq) → 2C_{2}H_{5}OH(aq) + 2CO_{2}(aq)When this process occurs in a closed container, the CO_{2} produced dissolves in the liquid, only to be released from solution when the container is opened. Most fine sparkling wines and champagnes are turned into carbonated beverages this way. Less-expensive sparkling wines are made like sodas and beer, with exposure to high pressures of CO_{2} gas.
What is the total pressure of a gas mixture containing these partial pressures: ${P}_{{\text{N}}_{2}}=0.78\text{atm}$, ${P}_{{\text{H}}_{2}}=0.33\text{atm}$, and ${P}_{{\text{O}}_{2}}=1.59\text{atm}$?
What is the total pressure of a gas mixture containing these partial pressures: P_{Ne} = 312 torr, P_{He} = 799 torr, and P_{Ar} = 831 torr?
In a gas mixture of He and Ne, the total pressure is 335 torr and the partial pressure of He is 0.228 atm. What is the partial pressure of Ne?
In a gas mixture of O_{2} and N_{2}, the total pressure is 2.66 atm and the partial pressure of O_{2} is 888 torr. What is the partial pressure of N_{2}?
A 3.55 L container has a mixture of 56.7 g of Ar and 33.9 g of He at 33°C. What are the partial pressures of the gases and the total pressure inside the container?
A 772 mL container has a mixture of 2.99 g of H_{2} and 44.2 g of Xe at 388 K. What are the partial pressures of the gases and the total pressure inside the container?
A sample of O_{2} is collected over water in a 5.00 L container at 20°C. If the total pressure is 688 torr, how many moles of O_{2} are collected?
A sample of H_{2} is collected over water in a 3.55 L container at 50°C. If the total pressure is 445 torr, how many moles of H_{2} are collected?
A sample of CO is collected over water in a 25.00 L container at 5°C. If the total pressure is 0.112 atm, how many moles of CO are collected?
A sample of NO_{2} is collected over water in a 775 mL container at 25°C. If the total pressure is 0.990 atm, how many moles of NO_{2} are collected?
A sample of NO is collected over water in a 75.0 mL container at 25°C. If the total pressure is 0.495 atm, how many grams of NO are collected?
A sample of ClO_{2} is collected over water in a 0.800 L container at 15°C. If the total pressure is 1.002 atm, how many grams of ClO_{2} are collected?
Determine the mole fractions of each component when 44.5 g of He is mixed with 8.83 g of H_{2}.
Determine the mole fractions of each component when 9.33 g of SO_{2} is mixed with 13.29 g of SO_{3}.
In a container, 4.56 atm of F_{2} is combined with 2.66 atm of Cl_{2}. What are the mole fractions of each component?
In a container, 77.3 atm of SiF_{4} are mixed with 33.9 atm of O_{2}. What are the mole fractions of each component?
2.70 atm
162 torr, or 0.213 atm
P_{Ar} = 10.0 atm; P_{He} = 59.9 atm; P_{tot} = 69.9 atm
0.183 mol
0.113 mol
0.0440 g
${\chi}_{\text{He}}=0.\text{718}$; ${\chi}_{{\text{H}}_{\text{2}}}=0.\text{282}$
${\chi}_{{\text{F}}_{\text{2}}}=0.\text{632}$; ${\chi}_{{\text{Cl}}_{\text{3}}}=0.\text{368}$