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The kinetic theory of gases indicates that gas particles are always in motion and are colliding with other particles and the walls of the container holding them. Although collisions with container walls are elastic (i.e., there is no net energy gain or loss because of the collision), a gas particle does exert a force on the wall during the collision. The accumulation of all these forces distributed over the area of the walls of the container causes something we call pressure. PressureForce per unit area. (P) is defined as the force of all the gas particle/wall collisions divided by the area of the wall:
$$\text{pressure}=\frac{\text{force}}{\text{area}}$$All gases exert pressure; it is one of the fundamental measurable quantities of this phase of matter. Even our atmosphere exerts pressure—in this case, the gas is being “held in” by the earth’s gravity, rather than the gas being in a container. The pressure of the atmosphere is about 14.7 pounds of force for every square inch of surface area: 14.7 lb/in^{2}.
Pressure has a variety of units. The formal, SI-approved unit of pressure is the pascal (Pa), which is defined as 1 N/m^{2} (one newton of force over an area of one square meter). However, this is usually too small in magnitude to be useful. A common unit of pressure is the atmosphereA unit of pressure equal to the average atmospheric pressure at sea level; defined as exactly 760 mmHg. (atm), which was originally defined as the average atmospheric pressure at sea level.
However, “average atmospheric pressure at sea level” is difficult to pinpoint because of atmospheric pressure variations. A more reliable and common unit is millimeters of mercuryThe amount of pressure exerted by a column of mercury exactly 1 mm high. (mmHg), which is the amount of pressure exerted by a column of mercury exactly 1 mm high. An equivalent unit is the torrAnother name for a millimeter of mercury., which equals 1 mmHg. (The torr is named after Evangelista Torricelli, a seventeenth-century Italian scientist who invented the mercury barometer.) With these definitions of pressure, the atmosphere unit is redefined: 1 atm is defined as exactly 760 mmHg, or 760 torr. We thus have the following equivalences:
$$\text{1atm}=\text{76}0\text{mmHg}=\text{76}0\text{torr}$$We can use these equivalences as with any equivalences—to perform conversions from one unit to another. Relating these to the formal SI unit of pressure, 1 atm = 101,325 Pa.
How many atmospheres are there in 595 torr?
Solution
Using the pressure equivalences, we construct a conversion factor between torr and atmospheres: $\frac{\text{1atm}}{760\text{torr}}$. Thus,
$$\text{595}\overline{)\text{torr}}\text{\hspace{0.17em}}\times \text{\hspace{0.17em}}\frac{1\text{atm}}{\text{760}\overline{)\text{torr}}}=0.783\text{atm}$$Because the numbers in the conversion factor are exact, the number of significant figures in the final answer is determined by the initial value of pressure.
Test Yourself
How many atmospheres are there in 1,022 torr?
Answer
1.345 atm
The atmosphere on Mars is largely CO_{2} at a pressure of 6.01 mmHg. What is this pressure in atmospheres?
Solution
Use the pressure equivalences to construct the proper conversion factor between millimeters of mercury and atmospheres.
$$6.01\overline{)\text{mmHg}}\text{\hspace{0.17em}}\times \text{\hspace{0.17em}}\frac{1\text{atm}}{760\overline{)\text{mmHg}}}=0.00791\text{atm}=\text{7}\text{.91}\text{\hspace{0.17em}}\times \text{\hspace{0.17em}}{\text{10}}^{-3}\text{atm}$$At the end, we expressed the answer in scientific notation.
Test Yourself
Atmospheric pressure is low in the eye of a hurricane. In a 1979 hurricane in the Pacific Ocean, a pressure of 0.859 atm was reported inside the eye. What is this pressure in torr?
Answer
652 torr
Define pressure. What causes it?
Define and relate three units of pressure.
If a force of 16.7 N is pressed against an area of 2.44 m^{2}, what is the pressure in pascals?
If a force of 2,546 N is pressed against an area of 0.0332 m^{2}, what is the pressure in pascals?
Explain why the original definition of atmosphere did not work well.
What units of pressure are equal to each other?
How many atmospheres are in 889 mmHg?
How many atmospheres are in 223 torr?
How many torr are in 2.443 atm?
How many millimeters of mercury are in 0.334 atm?
How many millimeters of mercury are in 334 torr?
How many torr are in 0.777 mmHg?
How many pascals are there in 1 torr?
A pressure of 0.887 atm equals how many pascals?
Pressure is force per unit area. It is caused by gas particles hitting the walls of its container.
6.84 Pa
Because the atmospheric pressure at sea level is variable, it is not a consistent unit of pressure.
1.17 atm
1,857 torr
334 mmHg
133 Pa